I haven't met an Undernet IRCop yet, but I really prefer Undernet over EFnet. Mainly because there are fewer people, so you get to know the regulars quickly. Of course, having a smaller population is also a bad thing if you're into some obscure topic or looking for a local scene. But places like #Computers, #Programming, and #C have enough people to entertain you.

Don't get me wrong though, Undernet isn't perfect, places like #C++ are places to stay away from. Overall though it's a good community.