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In substances where the current density J is proportional to the applied electric field E (i.e. where Ohm's law holds) the electrical conductivity σ may be defined,

JE
σ is expressed in Siemens per meter where 1 Siemens is 1 Ampere per Volt. Electrial conductivity is the inverse of resistivity ρ.

What follows is the derivation of an expression for σ where a steady electric field is applied to a conductor.

In a conductor there are conduction electrons which experience collisional and electrial forces. They acquire a net drift velocity vd in the opposite direction to J and E. These two forces eventually balance. (An analogy is terminal velocity in freefall where gravity and viscosity are the forces which balance)

The collisional force can be expressed (as in kinetic theory) as the momentum mevd divided by the collisional time τc where meis the electron mass. The electrical force is -eE where e is the electronic charge. Equating these forces one obtains-

-eE=mevdc
The current density J of electrons is proportional to the charge, velocity of charge carriers (-e) and the density ne of charge carriers-
J=-nee vd
Making a substitution for the drift velocity it follows-
E=(me/nee2τc) J
Comparing this expression with the original one for σ one obtains-
σ=nee2τc/me
From this equation it is clear that a good conductor (high σ) has a long collisional time.

Some σ values (source 'Electromagnetic Fields and Waves' by P.Lorrain, D.R.Corson, F.Lorrain and published by Freeman) expressed in Siemens/meter
Aluminium 3.54 X 107
Copper 5.80 X 107
Graphite 7.1 X 104
Seawater 5

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