in photography, PC stands for Prontor-Compur (two brands of shutters), and it identifies that little coaxial connector that you will find on most old cameras and on all professional cameras and studio flashes.
It is usually found on a PC cable, and its function is to synchronize the flash with the shutter, that's to say, to fire the flash when the shutter is fully open.

It is very old technology. Basically, you connect the flash and the camera with PC cable, and when the shutter opens the camera short-circuits the two wires, and the flash goes off.

In some old flash systems you will find quite a robust voltage on the PC connector, so don't put it in your mouth.